| Title |
Femtosecond laser ablation of a bulk graphite target in water for polyyne and nanomaterial synthesis / |
| Authors |
Semaltianos, Nikolaos G ; Balachninaitė, Ona ; Juškėnas, Remigijus ; Drabavičius, Audrius ; Niaura, Gediminas ; Hendry, Euan |
| DOI |
10.3390/app131810388 |
| Full Text |
|
| Is Part of |
Applied sciences.. Basel : MDPI AG. 2023, vol. 13, iss. 18, art. no. 10388, p. 1-14.. eISSN 2076-3417 |
| Keywords [eng] |
laser ablation ; nanoparticles ; colloids ; polyynes ; graphite |
| Abstract [eng] |
Laser ablation of a bulk graphite target in water using femtosecond laser pulses (pulse width ≤ 190 fs) was performed to investigate the synthesis of polyynes and carbon-based nanomaterials and compare them with the well-studied cases of longer pulse (picosecond or nanosecond) ablations. The laser ablation products were characterized using UV-vis absorption spectroscopy, Raman spectroscopy, X-ray diffraction, and transmission electron microscopy, whereas the induced plasma plumes were characterized using laser-induced breakdown spectroscopy. Carbon-based nanomaterials and short-chain polyynes (C6H2 and C8H2) are formed in the solutions as proven by their characteristic absorption band at ~262 nm and peaks in the region of 190–240 nm as well as at around 2100 cm−1 in the Raman spectra, respectively. Polyynes (C8H2) are present in the solutions that are produced under an ablation that is carried out in two intervals with a short pause between them, which is contrary to a continuous ablation that is performed for the same total time duration. The ablation products have a hexagonal graphite crystal structure. The carbon-based nanomaterials consist of large non-spherical and small spherical nanoparticles as well as sheet-like structures. The results of the study were compared with previous studies and discussed based on those studies. |
| Published |
Basel : MDPI AG |
| Type |
Journal article |
| Language |
English |
| Publication date |
2023 |
| CC license |
|
