Title Biomimetiniai (metil)naftochinono omega-merkapto darinių savitvarkiai monosluoksniai ant aukso ir sidabro paviršių: elektrocheminiai ir spektroskopiniai redokso virsmų ir struktūros tyrimai /
Translation of Title Self-assembled monolayers of biomimetic (methyl)naphthoquinone omega-derivatives on gold and silver surfaces: electrochemical and spectroscopic studies of redox conversion and structure.
Authors Bulovas, Arūnas
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Pages 145
Keywords [eng] naphthoquinones ; monolayers ; electrochemistry ; spectroscopy
Abstract [eng] A large set of biomimetic 1,4-naphthoquinone mercapto derivatives, varying in the side-chain length and intrachain functional groups, was synthesized. Structure and interfacial redox conversion of self-assembled monolayers on gold and silver surfaces, formed from newly synthesized compounds, were studied by cyclic voltammetry and surface-enhanced Raman spectroscopy. Low-density naphthoquinone-based monolayers were studied more thoroughly. Mixed monolayers of 1,4-naphthoquinone derivatives with different redox inactive alkylthiols were compared.
Type Doctoral thesis
Language Lithuanian
Publication date 2010