Title |
Self-assembled monolayers of biomimetic (methyl)naphthoquinone omega-mercapto derivatives on gold and silver surfaces: electrochemical and spectroscopic studies of redox conversion and structure / |
Translation of Title |
Biomimetiniai (metil)naftochinono omega-merkapto darinių savitvarkiai monosluoksniai ant aukso ir sidabro paviršių: elektrocheminiai ir spektroskopiniai redokso virsmų ir struktūros tyrimai. |
Authors |
Bulovas, Arūnas |
Full Text |
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Pages |
31 |
Keywords [eng] |
naphthoquinones ; monolayers ; electrochemistry ; spectroscopy |
Abstract [eng] |
A large set of biomimetic 1,4-naphthoquinone mercapto derivatives varying in the side-chain length and intrachain functional groups was synthesized. Interfacial redox processes and fine structure of self-assembled monolayers formed from newly synthesized compounds on gold and silver were studied by cyclic voltammetry and surface-enhanced Raman spectroscopy.Mixed monolayers of naphthoquinone derivatives and different redox inactive alkylthiols were studied. Low-density naphthoquinone-based monolayers were studied more thoroughly. |
Type |
Summaries of doctoral thesis |
Language |
English |
Publication date |
2010 |