| Title |
Dielectric and ultrasonic properties of PDMS/TiO2 nanocomposites / |
| Authors |
Vanskevičė, Ieva ; Kinka, Martynas ; Banys, Jūras ; Macutkevič, Jan ; Schaefer, Sebastien ; Selskis, Algirdas ; Fierro, Vanessa ; Celzard, Alain |
| DOI |
10.3390/polym16050603 |
| Full Text |
|
| Is Part of |
Polymers.. Basel : MDPI AG. 2024, vol. 16, iss. 5, art. no. 603, p. 1-14.. eISSN 2073-4360 |
| Keywords [eng] |
dielectric permittivity ; Vogel–Fulcher law ; titanium dioxide |
| Abstract [eng] |
This work presents the dielectric and ultrasonic properties of polydimethylsiloxane (PDMS) nanocomposites filled with titanium dioxide nanoparticles. The dielectric study was performed over a very broad range of frequencies (20 Hz–3 THz). The dielectric permittivity was almost frequency-independent in all the composites at room temperature over the whole range of measurement frequencies, and the dielectric losses were very low under these conditions (less than 2). The dielectric permittivity strongly increases with the nanoparticle concentration according to the Maxwell–Garnet model. Therefore, the investigated composites are suitable for various flexible electronic applications, particularly in the microwave and terahertz frequency ranges. Dielectric dispersion and increased attenuation of ultrasonic waves were observed at lower temperatures (below 280 K) due to the relaxation of polymer molecules at the PDMS/TiO2 interface and in the polymer matrix. The relaxation time followed the Vogel–Vulcher law, while the freezing temperature increased with the titanium dioxide concentration due to interactions between the polymer molecules and nanoparticles. The significant hysteresis in the ultrasonic properties indicated that titanium dioxide acts as a crystallization center. This is confirmed by the correlation between the hysteresis in the ultrasonic properties and the structure of the composites. The small difference in the activation energy values obtained from the ultrasonic and dielectric investigations is related to the fact that the dielectric dispersion is slightly broader than the Debye-type dielectric dispersion. |
| Published |
Basel : MDPI AG |
| Type |
Journal article |
| Language |
English |
| Publication date |
2024 |
| CC license |
|
