| Title |
Nature of the dielectric anomaly in Na0.5Bi0.5TiO3–based ferrolectrics |
| Authors |
Birks, Eriks ; Dunce, Marija ; Svirskas, Šarūnas ; Kežionis, Algimantas ; Banys, Jūras ; Kholkin, Andrei |
| DOI |
10.3390/ma18235289 |
| Full Text |
|
| Is Part of |
Materials.. Basel : MDPI. 2025, vol. 18, iss. 23, art. no. 5289, p. [1-19].. eISSN 1996-1944 |
| Keywords [eng] |
dielectric anomaly ; ferroelectric relaxors ; phase transition |
| Abstract [eng] |
The temperature–frequency dependence of dielectric permittivity in Na0.5Bi0.5TiO3 (NBT) -based compositions displays a diffused, frequency-independent maximum along with a frequency-dependent shoulder below this maximum. This behavior deviates from that of both classical ferroelectrics and conventional relaxor ferroelectrics, and its interpretation is further complicated by challenges in linking it to known structural phase transitions. This study proposes a new interpretation of the dielectric behavior of NBT-based materials through a comparative analysis of temperature–frequency permittivity data in both unpoled and poled NBT samples and 0.95Na0.5Bi0.5TiO3–0.05CaTiO3 solid solution over a broad frequency range (10 Hz–100 MHz). Results reveal that the steep permittivity change between the maximum and shoulder—accompanied by pronounced thermal hysteresis—can be attributed to a phase transition between two non-ferroelectric phases. When this contribution is excluded, the dielectric response aligns with classical relaxor ferroelectric behavior. To reconcile this with other known properties of NBT, the “breathing” model is employed, offering a unified framework for understanding its relaxor-like characteristics. |
| Published |
Basel : MDPI |
| Type |
Journal article |
| Language |
English |
| Publication date |
2025 |
| CC license |
|
